Using bio-based CaCO3 functionalized sediment to simultaneously remove algae and COD through adsorption and sedimentation in water source reservoirs
Highlights
a School of Civil Engineering, Chang’an University, Xi’an 710064, China.
b Key Laboratory of Environmental Aquatic Chemistry, State Key Laboratory of Regional Environment and Sustainability, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
c University of Chinese Academy of Sciences, Beijing 100049, China.
* Corresponding to: Jinyi Qin (jinyi.qin@chd.edu.cn), Ming Su (mingsu@rcees.ac.cn)
- Bio-CaCO3-modified sediment traps algae and COD via EPS bridging.
- Nanostructured CaCO3 forms core–shell clusters with active surface sites.
- Pores and charge heterogeneity promote selective pollutant retention.
- DFT reveals strong EPS–CaCO3 interaction at molecular level.
- System optimization achieved by RSM and XDLVO energy modeling.